Directed nucleophilic addition of phenoxides to cyclopropenes,Organic & Biomolecular Chemistry

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Directed nucleophilic addition of phenoxides to cyclopropenes
Organic & Biomolecular Chemistry ( IF 2.9 ) Pub Date : 2017-09-11 00:00:00 , DOI: 10.1039/c7ob01785e
Pavel Yamanushkin _{1,

2,

3,

4} , Michael Lu-Diaz _{1,

1,

2,

3,

4} , Andrew Edwards _{1,

2,

3,

4} , Nicolai A. Aksenov _{1,

5,

6,

7} , Marina Rubina _{1,

2,

3,

4,

8} , Michael Rubin _{1,

1,

2,

3,

4}

Affiliation

The alkali metal-templated addition of aryloxides across the double bond of non-conjugated cyclopropenes is described. High cis-selectivity is achieved through a directing effect of a strategically positioned carboxamide functionality.

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