Efficient electrosynthesis of phosphinic amides via oxidative cross-coupling between N–H/P–H,Green Chemistry

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Efficient electrosynthesis of phosphinic amides via oxidative cross-coupling between N–H/P–H
Green Chemistry ( IF 9.8 ) Pub Date : 2017-09-04 00:00:00 , DOI: 10.1039/c7gc01989k
Yukang Wang _{1,

2,

3,

4,

5} , Peng Qian _{1,

2,

3,

4,

5} , Ji-Hu Su _{3,

4,

5,

6,

7} , Yanan Li _{1,

2,

3,

4,

5} , Meixiang Bi _{1,

2,

3,

4,

5} , Zhenggen Zha _{1,

2,

3,

4,

5} , Zhiyong Wang _{1,

2,

3,

4,

5}

Affiliation

A facile and efficient approach to phosphinic amides was developed from diarylphosphine oxides and amines via electrosynthesis. A variety of phosphinic amides were obtained in one step with good to excellent yields under mild and metal-free conditions. The corresponding mechanism was investigated.

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