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Front Cover Picture: Gram‐Scale Synthesis of Amines Bearing a gem‐Difluorocyclopropane Moiety (Adv. Synth. Catal. 18/2017)
Advanced Synthesis & Catalysis ( IF 5.4 ) Pub Date : 2017-09-18 , DOI: 10.1002/adsc.201701120
Pavel S. Nosik 1, 2 , Andrii O. Gerasov 1 , Rodion O. Boiko 1 , Eduard Rusanov 2 , Sergey V. Ryabukhin 3 , Oleksandr O. Grygorenko 3 , Dmitriy M. Volochnyuk 2
Affiliation  

The front cover image, provided by Pavel Nosik, Andriy Gerasov, Sergey Ryabukhin, Oleksandr Grygorenko, and Dmitriy Volochnyuk illustrates the synthesis of secondary amines bearing a gem‐difluorocyclopropane moiety via reaction of unsaturated N‐Boc derivatives with the CF3SiMe3−NaI system. For the reactive alkenes, the standard reaction conditions can be used, whereas for those substrates with low reactivity, slow addition of the Ruppert‐Prakash reagent is necessary. (Background artwork by Web Design Studio “ZORELiT”). Details can be found in the full paper on pages 3126–3136 (P. S. Nosik, A. O. Gerasov, R. O. Boiko, E. Rusanov, S. V. Ryabukhin, O. O. Grygorenko, D. M. Volochnyuk, Adv. Synth. Catal. 2017, 359, 3126–3136; DOI: 10.1002/adsc.201700857).
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中文翻译:

封面图片:革-二氟环丙烷部分胺的克级合成(高级合成,目录号18/2017)

封面图片,由帕维尔Nosik,安德烈Gerasov,塞吉Ryabukhin,奥列克Grygorenko,和德米特里Volochnyuk提供示出仲胺的带有合成宝石-difluorocyclopropane部分通过不饱和的反应Ñ与CF -Boc衍生物3森达3 -NaI系统。对于反应性烯烃,可以使用标准反应条件,而对于那些低反应性的底物,则需要缓慢添加Ruppert-Prakash试剂。(Web设计工作室“ ZORELiT”提供的背景艺术品)。可以在第3126-3136页的全文中找到详细信息(P. S. Nosik,AO Gerasov,R。O. Boiko,E。Rusanov,S。V. Ryabukhin,OO Grygorenko,D。M. Volochnyuk,进阶 合成器。Catal2017年359,3126-3136; DOI:10.1002 / adsc.201700857)。
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更新日期:2017-09-18
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