Enantioselective Construction of All‐Carbon Quaternary Stereogenic Centers by Using Phosphine Catalysis,Asian Journal of Organic Chemistry

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Enantioselective Construction of All‐Carbon Quaternary Stereogenic Centers by Using Phosphine Catalysis
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2017-06-30 , DOI: 10.1002/ajoc.201700220
Huilin Li ₁ , Yixin Lu _{1,

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Affiliation

The asymmetric construction of all‐carbon quaternary stereogenic centers represents one of the most‐challenging tasks in organic synthesis, and it has drawn continuous attention from the synthetic community. Asymmetric phosphine catalysis has progressed at an astonishingly rate over the past decade and it offers the efficient creation of a diverse range of structural architectures. In this Focus Review, synthetic methods based on phosphine catalysis for the enantioselective construction of all‐carbon quaternary stereogenic centers are highlighted.

中文翻译：

磷化氢催化全碳四元立体异构中心的对映选择性构建

全碳四元立体异构中心的不对称结构代表了有机合成中最具挑战性的任务之一，并引起了合成界的持续关注。在过去的十年中，不对称膦的催化以惊人的速度发展，它可以有效地创建各种结构体系。在本《聚焦评论》中，重点介绍了基于膦催化的全碳四元立体异构中心对映选择性构建的合成方法。

更新日期：2017-06-30

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