Acyclic Quaternary Carbon Stereocenters via Enantioselective Transition Metal Catalysis,Chemical Reviews

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Acyclic Quaternary Carbon Stereocenters via Enantioselective Transition Metal Catalysis
Chemical Reviews ( IF 51.4 ) Pub Date : 2017-09-14 00:00:00 , DOI: 10.1021/acs.chemrev.7b00385
Jiajie Feng ₁ , Michael Holmes ₁ , Michael J Krische ₁

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Whereas numerous asymmetric methods for formation of quaternary carbon stereocenters in cyclic systems have been documented, the construction of acyclic quaternary carbon stereocenters with control of absolute stereochemistry remains a formidable challenge. This Review summarizes enantioselective methods for the construction of acyclic quaternary carbon stereocenters from achiral or chiral racemic reactants via transition metal catalysis.

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