Hydrogen-bonded Two-fold Interpenetrated Diamondoid Networks for Solid-State [2 + 2] Polymerizations of Criss-crossed Olefins: Molecular Connections vs Supramolecular Connections,Crystal Growth & Design

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Hydrogen-bonded Two-fold Interpenetrated Diamondoid Networks for Solid-State [2 + 2] Polymerizations of Criss-crossed Olefins: Molecular Connections vs Supramolecular Connections
Crystal Growth & Design ( IF 3.2 ) Pub Date : 2017-09-14 00:00:00 , DOI: 10.1021/acs.cgd.7b01114
Rajorshi Mandal ₁ , Mousumi Garai ₁ , Kumar Biradha ₁

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The molecular isomers of a diene-containing amide and pyridine moieties revealed that they exhibit different crystal structures and reactivities. One of the isomer forms a two-fold interpenetrated diamonded network via N–H···N hydrogen bonds and undergoes a [2 + 2] photopolymerization in the solid-state despite having unfavorable criss-cross aligned double bonds.

中文翻译：

氢键交叉互穿的类金刚石网络，用于固态[2 + 2]聚合的交叉烯烃的分子连接与超分子连接。

含二烯的酰胺和吡啶部分的分子异构体显示它们表现出不同的晶体结构和反应性。尽管有不利的纵横交错排列的双键，但其中一种异构体通过N·H··N氢键形成了两个互穿的菱形网络，并在固态下进行了[2 + 2]光聚合。

更新日期：2017-09-15

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