当前位置:
X-MOL 学术
›
Adv. Synth. Catal.
›
论文详情
Our official English website, www.x-mol.net, welcomes your
feedback! (Note: you will need to create a separate account there.)
The Base‐Promoted Annulation of 2‐Hydrazinyl Pyridine and CO2 toward Triazolones
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2017-09-26 , DOI: 10.1002/adsc.201700869 Xiaopeng Wu 1 , Song Sun 1 , Bingbing Wang 1 , Jiang Cheng 1
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2017-09-26 , DOI: 10.1002/adsc.201700869 Xiaopeng Wu 1 , Song Sun 1 , Bingbing Wang 1 , Jiang Cheng 1
Affiliation
A base‐promoted annulation of 2‐hydrazinyl pyridine and atmospheric pressure of CO2 has been developed in the presence of silane as reducing reagent, affording a series of triazolones in moderate to excellent yields. CO2 served as a carbonyl source in this transfomation. Moreover, benzamidrazones also worked well under this procedure. Thus, it represents a green, sustainable and straightforward pathway to access triazolone frameworks.
中文翻译:
碱促进的2-肼基吡啶和二氧化碳向三唑酮的环化
在硅烷作为还原剂存在下,开发了碱促进的2-肼基吡啶环化反应和大气压下的CO 2,可提供中等至极好的收率的三唑酮系列。在这种转化过程中,CO 2用作羰基来源。此外,苯并dra唑酮在该程序下也能很好地工作。因此,它代表了访问三唑酮框架的绿色,可持续和直接途径。
更新日期:2017-09-26
中文翻译:
碱促进的2-肼基吡啶和二氧化碳向三唑酮的环化
在硅烷作为还原剂存在下,开发了碱促进的2-肼基吡啶环化反应和大气压下的CO 2,可提供中等至极好的收率的三唑酮系列。在这种转化过程中,CO 2用作羰基来源。此外,苯并dra唑酮在该程序下也能很好地工作。因此,它代表了访问三唑酮框架的绿色,可持续和直接途径。