Rapid Synthesis of Rhodium–Palladium Alloy Nanocatalysts,ChemCatChem

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Rapid Synthesis of Rhodium–Palladium Alloy Nanocatalysts
ChemCatChem ( IF 3.8 ) Pub Date : 2017-09-14 04:42:07 , DOI: 10.1002/cctc.201701133
Graham W. Piburn ₁ , Hao Li ₁ , Pranaw Kunal ₁ , Graeme Henkelman ₁ , Simon M. Humphrey ₁

Affiliation

A good mix: Near-monodisperse RhPd alloy nanoparticles are prepared by a rapid (30 s) hot-injection method under microwave heating. The particles are active hydrogenation catalysts and are more stable than pure Rh nanoparticles at longer reaction times. DFT studies show that Rh-to-Pd charge transfer permits tunability of H and alkene binding energies.

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