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Ni(II) complex on a bispyridine-based porous organic polymer as a heterogeneous catalyst for ethylene oligomerization
Catalysis Science & Technology ( IF 5 ) Pub Date : 2017-09-04 00:00:00 , DOI: 10.1039/c7cy01274h
Min Jeong Kim 1, 2, 3, 4, 5 , Sol Ahn 6, 7, 8, 9 , Jigyoung Yi 1, 2, 3, 4, 5 , Joseph T. Hupp 1, 7, 8, 9 , Justin M. Notestein 6, 7, 8, 9 , Omar K. Farha 1, 1, 7, 8, 9 , Suk Joong Lee 1, 2, 3, 4, 5
Affiliation  

A Ni(II) catalyst incorporated into a new porous organic polymer, Ni(II)-POP-1, is prepared via a click reaction followed by metalation with NiCl2. It shows good catalytic activity for liquid-phase ethylene dimerization in the presence of Et2AlCl as a co-catalyst, generating 1-butene.

中文翻译:

吡啶基多孔有机聚合物上的Ni(II)络合物作为乙烯低聚反应的非均相催化剂

通过点击反应,然后用NiCl 2进行金属化,制备了掺入新的多孔有机聚合物Ni(II)-POP- 1中的Ni(II)催化剂。它在Et 2 AlCl作为助催化剂存在下,对液相乙烯二聚反应显示出良好的催化活性,生成了1-丁烯。
更新日期:2017-09-14
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