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On the use of ferroelectric material LiNbO3 as novel photocatalyst in wastewater-fed microbial fuel cells
Particuology ( IF 4.1 ) Pub Date : 2017-06-16 , DOI: 10.1016/j.partic.2017.02.006
N. Touach , V.M. Ortiz-Martínez , M.J. Salar-García , A. Benzaouak , F. Hernández-Fernández , A. P. de Ríos , M. El Mahi , E.M. Lotfi

In this work, the use of lithium niobate (LiNbO3), a ferroelectric and photocatalyst material, is investigated as a new type of cathode catalyst for wastewater-fed single-chamber microbial fuel cells (MFCs). Carbon cloth electrodes coated with LiNbO3 were studied with and without UV–vis irradiation to assess its photocatalytic behavior in these devices. The synthesized phase of LiNbO3 was characterized by X-ray diffraction, differential scanning calorimetry, particle size distribution, and transmission electron microscopy analyses. The MFC containing a LiNbO3-based cathode exhibited a maximum open circuit potential and power output of 400 mV and 131 mW/m3, respectively, under irradiation. This cathode configuration also achieved the maximum chemical oxygen demand removal of 84% after 120 h of MFC operation. These results show that ferroelectric materials such as LiNbO3 could be used as cathode catalysts in MFC devices. As a complementary analysis, the removal of the heavy metals detected in the wastewater was also monitored.



中文翻译:

铁电材料LiNbO 3在废水供养微生物燃料电池中作为新型光催化剂的应用

在这项工作中,研究了铌酸锂(LiNbO 3),一种铁电和光催化剂材料,作为一种新型的阴极废水处理单腔微生物燃料电池(MFCs)阴极催化剂。研究了在有和没有UV-vis照射下涂有LiNbO 3的碳布电极,以评估其在这些设备中的光催化行为。LiNbO 3的合成相通过X射线衍射,差示扫描量热法,粒度分布和透射电子显微镜分析进行表征。包含基于LiNbO 3的阴极的MFC表现出最大的开路电势和400 mV和131 mW / m 3的功率输出分别在照射下。在MFC运行120小时后,该阴极配置还实现了84%的最大化学需氧量去除。这些结果表明,诸如LiNbO 3的铁电材料可以用作MFC装置中的阴极催化剂。作为补充分析,还监测了废水中检测到的重金属的去除。

更新日期:2017-06-16
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