Rhodium(III)‐Catalyzed C−H Activation of O‐Acetyl Ketoximes/N‐Methoxybenzamides toward the Synthesis of Isoquinoline/Isoquinolone‐Fused Bicycles,Asian Journal of Organic Chemistry

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Rhodium(III)‐Catalyzed C−H Activation of O‐Acetyl Ketoximes/N‐Methoxybenzamides toward the Synthesis of Isoquinoline/Isoquinolone‐Fused Bicycles
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2017-08-30 , DOI: 10.1002/ajoc.201700377
Ajesh Vijayan _{1,

2} , Choorappulan Ummu Jumaila ₂ , Kokkuvayil Vasu Radhakrishnan _{1,

2}

Affiliation

An efficient rhodium(III)‐catalyzed C−H activation approach for the construction of fused heterocyclic motifs with urea‐derived bicyclic olefins has been demonstrated. A rhodium‐catalyzed reaction of O‐acetyl ketoximes with these bicyclic motifs furnished isoquinoline derivatives, whereas isoquinolone‐fused bicyclic olefins were obtained with the reaction of N‐methoxybenzamides.

中文翻译：

铑（III）催化邻乙酰酮肟/ N-甲氧基苯甲酰胺的CHH活化合成异喹啉/异喹诺酮类自行车

已经证明了一种有效的铑（III）催化的CH活化方法，可用于构建脲衍生的双环烯烃稠合的杂环基序。O-乙酰基酮肟与这些双环基元的铑催化反应提供了异喹啉衍生物，而异喹诺酮稠合的双环烯烃是通过N-甲氧基苯甲酰胺的反应获得的。

更新日期：2017-08-30

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