Cover Feature: Structural Characterization of Chirality‐Organized Ferrocene–Dipeptide Conjugates that Contain Pyridine N‐Oxide Moieties (Asian J. Org. Chem. 9/2017),Asian Journal of Organic Chemistry

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Cover Feature: Structural Characterization of Chirality‐Organized Ferrocene–Dipeptide Conjugates that Contain Pyridine N‐Oxide Moieties (Asian J. Org. Chem. 9/2017)
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2017-08-29 , DOI: 10.1002/ajoc.201700227
Toshiyuki Moriuchi ₁ , Hao Wu ₁ , Yoshiki Tayano ₁ , Toshikazu Hirao ₁

Affiliation

Time and peptide: Bioorganometallic ferrocene–dipeptide conjugate composed of two l‐Ala−l‐Pro dipeptides having the C‐terminal pyridine N‐oxide moieties, in which a P‐helical chirality of the ferrocenoyl moiety was induced through the formation of intramolecular antiparallel β‐sheet‐like hydrogen bonds, was shown to create self‐assembled structures through hydrogen bonding and π–π interactions between the pyridine N‐oxide moieties, resulting in a right‐handed molecular arrangement of the peptide chains. The introduction of only one dipeptide chain into the ferrocene organometallic scaffold led to a self‐assembled tetramer structure. More information can be found in the Full Paper by Toshiyuki Moriuchi, Toshikazu Hirao et al. on page 1250 in Issue 9, 2017 (DOI: 10.1002/ajoc.201700145).

中文翻译：

封面人物：含有吡啶N-氧化物部分的手性-有机二茂铁-二肽结合物的结构表征（Asian J. Org。Chem。9/2017）

时间和肽：由两个具有C末端吡啶N-氧化物部分的l- Ala- l- Pro二肽组成的生物有机金属二茂铁-二肽共轭物，其中二茂铁酰基部分的P螺旋手性是通过分子内反平行分子的形成诱导的研究表明，β-折叠状氢键通过氢键和吡啶N之间的π-π相互作用产生自组装结构。氧化部分，导致肽链的右旋分子排列。在二茂铁有机金属支架中仅引入一个二肽链导致了自组装四聚体结构。可以在Toshikazu Hirao等人的Moriuchi Toshiyuki的论文全文中找到更多信息。就在第9期2017年1250页（：10.1002 / ajoc.201700145 DOI）。

更新日期：2017-08-29

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