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Intramolecular Pd-Catalyzed Anomeric C(sp3)–H Activation of Glycosyl Carboxamides
Organic Letters ( IF 4.9 ) Pub Date : 2017-09-13 00:00:00 , DOI: 10.1021/acs.orglett.7b02170 Nicolas Probst 1 , Gwendal Grelier 2 , NourEddine Ghermani 3 , Vincent Gandon 2, 4 , Mouâd Alami 1 , Samir Messaoudi 1
Organic Letters ( IF 4.9 ) Pub Date : 2017-09-13 00:00:00 , DOI: 10.1021/acs.orglett.7b02170 Nicolas Probst 1 , Gwendal Grelier 2 , NourEddine Ghermani 3 , Vincent Gandon 2, 4 , Mouâd Alami 1 , Samir Messaoudi 1
Affiliation
An expedient method for the synthesis of fused glycosylquinolin-2-ones and glycosylspirooxindoles through an unprecedented intramolecular Pd-catalyzed anomeric C–H activation of the sugar moiety of 2-bromophenyl glycosylcarboxamides is reported. The scope of the reaction is broad and tolerates a wide range of functional groups.
中文翻译:
分子内钯催化的端基糖基羧酰胺的C(sp 3)–H活化
据报道,通过空前的分子内钯催化2-溴苯基糖基羧酰胺的糖基端基C–H活化,合成融合的糖基喹啉-2-酮和糖基螺硫辛酯的简便方法。反应的范围很广,并且可以容忍各种各样的官能团。
更新日期:2017-09-13
中文翻译:
分子内钯催化的端基糖基羧酰胺的C(sp 3)–H活化
据报道,通过空前的分子内钯催化2-溴苯基糖基羧酰胺的糖基端基C–H活化,合成融合的糖基喹啉-2-酮和糖基螺硫辛酯的简便方法。反应的范围很广,并且可以容忍各种各样的官能团。