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Palladium-Catalyzed ortho–C-H Arylation of Acetophenone Oxime Ethers with Aryl Pinacol Boronic Esters
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2017-09-13 00:00:00 , DOI: 10.1021/acs.joc.7b01524
Daggula Mallikarjuna Reddy,Shao-Chien Wang,Kai Du,Chin-Fa Lee

We report an efficient palladium-catalyzed ortho–C-H arylation of acetophenone oxime ethers with aryl pinacol boronic esters, leading to the synthesis of biaryl derivatives in good yields. Sequential process of iridium-catalyzed C–H borylation and palladium-catalyzed ortho–C-H arylation directed to access functionalized arenes.

中文翻译:

苯乙酮肟肟醚与芳基品那醇硼酸酯的钯催化邻位-CH芳基化

我们报告了苯乙酮肟醚与芳基频哪醇硼酸酯的高效钯催化邻位-CH芳基化反应,从而以高收率合成了联芳基衍生物。铱催化的CH硼化和钯催化的邻位-CH芳基化的顺序过程,涉及到官能化的芳烃。
更新日期:2017-09-13
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