Oxidative Heck Reaction as a Tool for Para-selective Olefination of Aniline: A DFT Supported Mechanism,The Journal of Organic Chemistry

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Oxidative Heck Reaction as a Tool for Para-selective Olefination of Aniline: A DFT Supported Mechanism
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2017-09-13 00:00:00 , DOI: 10.1021/acs.joc.7b01570
Firouz Matloubi Moghaddam ₁ , Raheleh Pourkaveh ₁ , Ashkan Karimi ₁

Affiliation

This study describes the first para-selective palladium-catalyzed alkenylation of tertiary amines. This regioselective C–H activation was conducted without any chelation moieties. A series of olefins were reacted under mild reaction conditions at 60 °C, and the corresponding products were obtained in good yields with high selectivity.

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