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Hot corrosion behavior and near-surface microstructure of a “Low-Temperature High-Activity Cr-aluminide” coating on Inconel 738LC exposed to Na 2 SO 4 , Na 2 SO 4 + V 2 O 5 and Na 2 SO 4 + V 2 O 5 + NaCl at 900 °C
Corrosion Science ( IF 7.4 ) Pub Date : 2017-11-01 , DOI: 10.1016/j.corsci.2017.09.004
M. Salehi Doolabi , B. Ghasemi , S.K. Sadrnezhaad , A. Habibollahzadeh , K. Jafarzadeh

Abstract Hot corrosion is a serious problem in gas turbines due to poor quality fuels which contain Na, V, S and Cl. To resolve the problem, Cr-aluminide was coated on IN-738LC superalloy with a two steps pack cementation process. Oxidation behavior and near-surface microstructure of the coating showed consecutive increase in destruction by exposition to Na2SO4, 75Na2SO4 + 25 V2O5 and 70Na2SO4 + 25 V2O5 + 5NaCl (wt.%). Kinetic studies indicated parabolic corrosion rate in salt-less samples due to diffusion. Similar expression for salt-covered samples was assessed for oxide dissolution. Plate-like, broken-plate-like and cauliflower-like morphologies attributed to the corrosion products were observed after exposition to above three salts, respectively.

中文翻译:

暴露于 Na 2 SO 4 、Na 2 SO 4 + V 2 O 5 和 Na 2 SO 4 + V 2 O 的 Inconel 738LC 上的“低温高活性 Cr-铝化物”涂层的热腐蚀行为和近表面微观结构5 + NaCl 900 °C

摘要 由于含有 Na、V、S 和 Cl 的劣质燃料,热腐蚀是燃气轮机中的一个严重问题。为了解决这个问题,采用两步填充胶结工艺在 IN-738LC 高温合金上涂覆 Cr-铝化物。涂层的氧化行为和近表面微观结构显示,暴露于 Na2SO4、75Na2SO4 + 25 V2O5 和 70Na2SO4 + 25 V2O5 + 5NaCl (wt.%) 后,破坏连续增加。动力学研究表明,由于扩散,无盐样品中的抛物线腐蚀速率。针对氧化物溶解评估盐覆盖样品的类似表达。在暴露于上述三种盐后,分别观察到由腐蚀产物引起的板状、碎板状和菜花状形态。
更新日期:2017-11-01
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