Phosphorus-based materials for high-performance rechargeable batteries,Inorganic Chemistry Frontiers

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Phosphorus-based materials for high-performance rechargeable batteries
Inorganic Chemistry Frontiers ( IF 6.1 ) Pub Date : 2017-07-12 00:00:00 , DOI: 10.1039/c7qi00184c
Xinyu Qin _{1,

2,

3,

4,

5} , Bingyi Yan _{1,

2,

3,

4,

5} , Jia Yu _{1,

2,

3,

4,

5} , Jie Jin _{1,

2,

3,

4,

5} , Yao Tao _{1,

2,

3,

4,

5} , Chao Mu _{1,

2,

3,

4,

5} , Sicong Wang _{1,

2,

3,

4,

5} , Huaiguo Xue _{1,

2,

3,

4,

5} , Huan Pang _{1,

2,

3,

4,

5}

Affiliation

Lithium/sodium ion secondary batteries are an ideal power source for electric vehicles, portable electronic devices and energy storage devices, and recent studies have found that they are more environmentally friendly than other batteries. Innovative research on new electrode materials is the foundation for the development of neoteric high-performance batteries. Phosphorus offers a high theoretical specific capacity and is naturally abundant, thus making it utilizable in electrode materials. At present, however, our understanding of phosphorous materials is deficient, which hinders its widespread development and application, especially in the area of energy storage. To address this issue, the properties of P allotropes have been reviewed in this work. We introduce the recent development of P as an electrode material for energy storage, including the preparation of composite materials and the influence of the structure of the material on its electrochemical properties, among others. Furthermore, this review highlights that distinct P structures modulate the electrochemical properties of the material. Finally, we present a vision of the future development of phosphorous materials in the energy storage field.

中文翻译：

高性能充电电池的磷基材料

锂/钠离子二次电池是电动汽车，便携式电子设备和能量存储设备的理想电源，最近的研究发现它们比其他电池更环保。新电极材料的创新研究是现代高性能电池开发的基础。磷具有很高的理论比容量，并且自然丰富，因此可在电极材料中使用。但是，目前，我们对磷材料的认识不足，这阻碍了磷材料的广泛开发和应用，特别是在储能领域。为了解决这个问题，这项工作对P同素异形体的性质进行了综述。我们介绍了P作为储能电极材料的最新进展，其中包括复合材料的制备以及材料结构对其电化学性能的影响等。此外，本综述强调了不同的P结构可调节材料的电化学性能。最后，我们对储能领域中磷材料的未来发展提出了展望。

更新日期：2017-09-12

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