Electrochemical Reduction of Protic Supercritical CO2 on Copper Electrodes,ChemSusChem

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Electrochemical Reduction of Protic Supercritical CO2 on Copper Electrodes
ChemSusChem ( IF 7.5 ) Pub Date : 2017-09-12 03:30:53 , DOI: 10.1002/cssc.201701205
Olga Melchaeva _{1,

2,

3} , Patrick Voyame ₁ , Victor Costa Bassetto ₁ , Michael Prokein ₃ , Manfred Renner ₃ , Eckhard Weidner _{2,

3} , Marcus Petermann ₂ , Alberto Battistel ₁

Affiliation

Super conversion: Electrochemical reduction of CO₂ in aqueous solutions is usually plagued with significant hydrogen evolution. The reduction of CO₂ in the supercritical phase can be tuned by adding different protic aqueous solutions, such as acidic, basic, or buffer solutions. Different selectivities are achieved and, for the first time, it is possible to convert supercritical CO₂ to methanol and ethanol.

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