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The characterization of natural gemstones using non-invasive FT-IR spectroscopy: New data on tourmalines
Talanta ( IF 5.6 ) Pub Date : 2017-09-11 , DOI: 10.1016/j.talanta.2017.09.030
Mariano Mercurio , Manuela Rossi , Francesco Izzo , Piergiulio Cappelletti , Chiara Germinario , Celestino Grifa , Maurizio Petrelli , Alessandro Vergara , Alessio Langella

Fourteen samples of tourmaline from the Real Museo Mineralogico of Federico II University (Naples) have been characterized through multi-methodological investigations (EMPA-WDS, SEM-EDS, LA-ICP-MS, and FT-IR spectroscopy). The samples show different size, morphology and color, and are often associated with other minerals. Data on major and minor elements allowed to identify and classify tourmalines as follows: elbaites, tsilaisite, schorl, dravites, uvites and rossmanite. Non-invasive, non-destructive FT-IR and in-situ analyses were carried out on the same samples to validate this chemically-based identification and classification. The results of this research show that a complete characterization of this mineral species, usually time-consuming and expensive, can be successfully achieved through non-destructive FT-IR technique, thus representing a reliable tool for a fast classification extremely useful to plan further analytical strategies, as well as to support gemological appraisals.



中文翻译:

使用非侵入式FT-IR光谱表征天然宝石:电气石的新数据

通过多方法研究(EMPA-WDS,SEM-EDS,LA-ICP-MS和FT-IR光谱法)对来自费德里科II大学(那不勒斯)真实矿物矿物学中的14个电气石样品进行了表征。样品显示出不同的大小,形态和颜色,并且经常与其他矿物质相关。关于主要元素和次要元素的数据可用于对电气石进行识别和分类,如下所示:硅铝石,硅铝石,鼠尾草,德拉瓦特,uvites和罗斯曼石。对相同样品进行了非侵入性,非破坏性的FT-IR和原位分析,以验证这种基于化学的鉴定和分类。这项研究的结果表明,通过无损FT-IR技术可以成功地完成对这种矿物质的完整表征,通常耗时且昂贵。

更新日期:2017-09-11
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