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An Electrochemical Method for Carboxylic Ester Synthesis from N-Alkoxyamides
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2017-09-11 00:00:00 , DOI: 10.1021/acs.joc.7b01473 Kripa Subramanian 1 , Subhash L. Yedage 1 , Bhalchandra M. Bhanage 1
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2017-09-11 00:00:00 , DOI: 10.1021/acs.joc.7b01473 Kripa Subramanian 1 , Subhash L. Yedage 1 , Bhalchandra M. Bhanage 1
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An electrochemical method for the synthesis of carboxylic as well as hindered esters from N-alkoxyamides has been reported. The electrochemical reaction proceeds through constant current electrolysis (CCE) by taking advantage of the dual role of n-Bu4NI (TBAI) as the redox catalyst as well as the supporting electrolyte. Besides providing mild reaction conditions, the present protocol is free from external oxidants and conducting salts, thereby generating nitrogen as the nonhazardous side product. Additionally, the developed procedure is highly advantageous due to its short reaction time, wide substrate scope, and gram-scale synthesis.
中文翻译：
N-烷氧基酰胺合成羧酸酯的电化学方法
已经报道了从N-烷氧基酰胺合成羧酸以及受阻酯的电化学方法。通过利用双重作用优点通过恒定电流电解（CCE）的电化学反应的进行Ñ -Bu 4 NI（TBAI）作为氧化还原催化剂，以及作为支持电解质。除了提供温和的反应条件外，本方案不含外部氧化剂和导电盐，从而产生氮作为无害副产物。另外，由于其反应时间短，底物范围宽和克级合成，因此开发的方法具有很高的优势。
更新日期：2017-09-11
中文翻译：
N-烷氧基酰胺合成羧酸酯的电化学方法
已经报道了从N-烷氧基酰胺合成羧酸以及受阻酯的电化学方法。通过利用双重作用优点通过恒定电流电解（CCE）的电化学反应的进行Ñ -Bu 4 NI（TBAI）作为氧化还原催化剂，以及作为支持电解质。除了提供温和的反应条件外，本方案不含外部氧化剂和导电盐，从而产生氮作为无害副产物。另外，由于其反应时间短，底物范围宽和克级合成，因此开发的方法具有很高的优势。
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