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Process-tolerant pressureless-sintered silicon carbide ceramics with alumina-yttria-calcia-strontia
Journal of the European Ceramic Society ( IF 5.8 ) Pub Date : 2017-09-11 , DOI: 10.1016/j.jeurceramsoc.2017.09.011
Yu-Kwang Seo , Jung-Hye Eom , Young-Wook Kim

Process-tolerant SiC ceramics were prepared by pressureless sintering at 1850–1950 °C for 2 h in an argon atmosphere with a new quaternary additive (Al2O3-Y2O3-CaO-SrO). The SiC ceramics can be sintered to a > 94% theoretical density at 1800–1950 °C by pressureless sintering. Toughened microstructures consisting of relatively large platelet grains and small equiaxed grains were obtained when SiC ceramics were sintered at 1850–1950 °C. The presently fabricated SiC ceramics showed little variability of the microstructure and mechanical properties with sintering within the temperature range of 1850–1950 °C, demonstrating process-tolerant behavior. The thermal conductivity of the SiC ceramics increased with increasing sintering temperature from 1800 °C to 1900 °C due to decreases of the lattice oxygen content of the SiC grains and residual porosity. The flexural strength, fracture toughness, and thermal conductivity of the SiC ceramics sintered at 1850–1950 °C were in the ranges of 444–457 MPa, 4.9–5.0 MPa m1/2, and 76–82 Wm−1 K−1, respectively.



中文翻译:

具有氧化铝-氧化钇-氧化锶-锶的耐过程无压烧结碳化硅陶瓷

耐过程的SiC陶瓷是通过在氩气气氛中于1850–1950°C进行2 h的无压烧结,并使用一种新的四元添加剂(Al 2 O 3 -Y 2 O 3-CaO-SrO)。SiC陶瓷可通过无压烧结在1800-1950°C的条件下烧结至理论密度> 94%。当在1850–1950°C的温度下烧结SiC陶瓷时,获得了由相对较大的片状晶粒和较小的等轴晶粒组成的增韧微结构。目前制造的SiC陶瓷在1850–1950°C的温度范围内进行烧结时,其微观结构和机械性能几乎没有变化,证明了其耐工艺性。SiC陶瓷的热导率随着烧结温度从1800°C到1900°C的增加而增加,这是由于SiC晶粒的晶格含氧量减少和残余孔隙率所致。在1850–1950°C烧结的SiC陶瓷的弯曲强度,断裂韧性和导热系数在444–457 MPa,4.9–5的范围内。分别为1/2和76-82 Wm -1  K -1

更新日期:2017-09-11
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