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Ambidentate Ligand Reactivity with the Rhenium(I) Compounds [BrRe(CO)4]2 and cis-BrRe(CO)4L: A Kinetic and Mechanistic Study
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2017-09-11 02:25:50 , DOI: 10.1002/ejic.201700538 Darrell D. Mayberry 1 , Vladimir N. Nesterov 1 , Michael G. Richmond 1
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2017-09-11 02:25:50 , DOI: 10.1002/ejic.201700538 Darrell D. Mayberry 1 , Vladimir N. Nesterov 1 , Michael G. Richmond 1
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The reaction of 2-(diphenylphosphanyl)pyridine with the dimer [BrRe(CO)4]2 has been modeled by DFT calculations. The pyridyl-coordinated isomer cis-BrRe(CO)4(κN-PN) is formed as the kinetic product of substitution, which in turn undergoes a rapid isomerization to furnish the thermodynamically more stable κP-isomer through a dissociative ligand process.
中文翻译：
与hen（I）化合物[BrRe（CO）4] 2和顺式BrRe（CO）4L的精确配体反应性：动力学和机理研究
2-（二苯基膦烷基）吡啶与二聚体[BrRe（CO）4 ] 2的反应已通过DFT计算进行了建模。所述吡啶基异构体配位顺-BrRe（CO）4（κ Ñ -PN）被形成为取代的动力学产物，而这又经历了一个快速的异构化，得到的热力学更稳定的κ P通过离解性配体-异构体的过程。
更新日期：2017-09-11
中文翻译：
与hen（I）化合物[BrRe（CO）4] 2和顺式BrRe（CO）4L的精确配体反应性：动力学和机理研究
2-（二苯基膦烷基）吡啶与二聚体[BrRe（CO）4 ] 2的反应已通过DFT计算进行了建模。所述吡啶基异构体配位顺-BrRe（CO）4（κ Ñ -PN）被形成为取代的动力学产物，而这又经历了一个快速的异构化，得到的热力学更稳定的κ P通过离解性配体-异构体的过程。
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