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Catalytic upgrading of bio-tar over a MgNiMo/activated charcoal catalyst under supercritical ethanol conditions
Catalysis Today ( IF 5.3 ) Pub Date : 2017-09-08 , DOI: 10.1016/j.cattod.2017.09.016
Jin-Hyuk Lee , In-Gu Lee , Wonjin Jeon , Jong-Hyeon Ha , Kwan-Young Lee

Upgrading of bio-tar derived from fast pyrolysis of sawdust was performed over activated charcoal supported nickel-based catalysts (Ni/AC, NiMo/AC, MgNiMo/AC) under supercritical ethanol conditions. The catalytic activities of the catalysts was compared with those of representative bio-oil upgrading catalysts (Ru/AC, HZSM-5). The MgNiMo/AC catalyst exhibited the highest catalytic performance among the catalysts with a decrease of oxygen content in bio-tar from 31.3 wt% up to 10.8 wt% and the yield of liquid product (75 wt%). The effects of reaction temperature (275–350 °C), reaction time (0–120 min) and bio-tar to ethanol ratio (1/9–4/6) were also studied over the MgNiMo/AC catalyst. In addition, reaction of vanillin which is one of major compounds present in bio-tar was carried out under the same bio-tar upgrading conditions in order to understand the production mechanism of phenolic chemicals.



中文翻译:

MgNiMo /活性炭催化剂上超临界乙醇条件下生物焦油的催化提质

在活性炭负载的镍基催化剂(Ni / AC,NiMo / AC,MgNiMo / AC)上,在超临界乙醇条件下,对源自木屑快速热解的生物焦油进行了升级。将催化剂的催化活性与代表性的生物油提质催化剂(Ru / AC,HZSM-5)进行了比较。在催化剂中,MgNiMo / AC催化剂表现出最高的催化性能,其中生物焦油中的氧含量从31.3 wt%降低到10.8 wt%,液体产品的收率(75 wt%)降低。在MgNiMo / AC催化剂上,还研究了反应温度(275–350°C),反应时间(0–120分钟)和生物焦油与乙醇之比(1 / 9–4 / 6)的影响。此外,

更新日期:2017-09-08
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