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Magnetophoretic Mole-Ratio Method
Analytical Chemistry ( IF 6.7 ) Pub Date : 2017-09-08 00:00:00 , DOI: 10.1021/acs.analchem.7b00999
Hitoshi Watarai 1 , Jiayue Chen 1
Affiliation  

The principle of the mole-ratio method utilizing magnetophoretic velocimetry was demonstrated for the first time. The feasibility of the magnetophoretic mole-ratio method was studied for the determination of the stoichiometry of the complexes formed between a hydrophobic phosphate ligand adsorbed in mesoporous hydrophobic silica particles and paramagnetic metal ions of Co(II), Tb(III), and Dy(III) in aqueous solutions. The present method is a nonspectroscopic method and carried out by a simple magnetic device.

中文翻译:

磁致动摩尔比法

首次证明了利用磁风速法的摩尔比方法的原理。研究了磁致摩尔比方法用于测定介孔疏水性二氧化硅颗粒中吸附的疏水性磷酸盐配体与Co(II),Tb(III)和Dy()的顺磁性金属离子形成的配合物的化学计量的可行性III)在水溶液中。本方法是非光谱方法,并且通过简单的磁性装置来实施。
更新日期:2017-09-08
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