Diels-Alder and Formal Diels-Alder Cycloaddition Reactions of Ynamines and Ynamides,European Journal of Organic Chemistry

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Diels-Alder and Formal Diels-Alder Cycloaddition Reactions of Ynamines and Ynamides
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2017-09-08 , DOI: 10.1002/ejoc.201700986
Guillaume Duret ₁ , Vincent Le Fouler ₁ , Philippe Bisseret ₁ , Vincent Bizet ₁ , Nicolas Blanchard ₁

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Nitrogen-substituted alkynes such as ynamines and ynamides are competent partners in [4+2] cycloaddition reactions. This microreview aims to discuss in a historical context the main achievements in the work on this class of reactions that leads to valuable nitrogen-containing heterocycles in a single-step fashion. In the last section, our own work in the field of inverse-electron-demand Diels–Alder reactions between ynamides and pyrimidines is discussed.

中文翻译：

Ynamines和Ynamides的Diels-Alder和Formal Diels-Alder环加成反应

氮取代的炔烃如 ynamines 和 ynamides 是 [4+2] 环加成反应的有效伙伴。这篇微观综述旨在在历史背景下讨论此类反应的主要成就，这些反应以一步方式产生有价值的含氮杂环。在最后一节中，我们讨论了我们自己在 ynamides 和嘧啶之间的反电子需求 Diels-Alder 反应领域的工作。

更新日期：2017-09-08

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