Harnessing the potential diversity of resinic diterpenes through visible light-induced sensitized oxygenation coupled to Kornblum–DeLaMare and Hock reactions,Organic Chemistry Frontiers

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Harnessing the potential diversity of resinic diterpenes through visible light-induced sensitized oxygenation coupled to Kornblum–DeLaMare and Hock reactions
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2017-08-31 00:00:00 , DOI: 10.1039/c7qo00633k
Benjamin Laroche _{1,

2,

3,

4,

5} , Bastien Nay _{1,

2,

3,

4,

5}

Affiliation

A biomimetic procedure for the late-stage functionalization of various resinic acids is reported, implementing photooxygenation by singlet oxygen, using visible light and meso-tetraphenylporphyrin, combined to the Kornblum–DeLaMare reaction or the Hock rearrangement. In addition to giving access to several natural and unnatural diterpenes by the simplest manner, these transformations furnish biosynthetic clues expandable to other natural product families.

中文翻译：

通过可见光诱导的敏化氧与Kornblum-DeLaMare和Hock反应耦合来利用树脂二萜的潜在多样性

有人报道了一种用于各种树脂酸后期官能化的仿生程序，利用可见光和内消旋四苯基卟啉通过单线态氧进行光氧合，并结合到Kornblum-DeLaMare反应或Hock重排中。除了以最简单的方式获得几种天然和非天然的二萜外，这些转化还提供了可扩展到其他天然产物家族的生物合成线索。

更新日期：2017-09-07

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