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N-Doped hollow carbon nanosheet supported SnO2 nanoparticles
Inorganic Chemistry Frontiers ( IF 7 ) Pub Date : 2017-08-18 00:00:00 , DOI: 10.1039/c7qi00399d
Heng Mao 1, 2, 3, 4, 5 , Lei Shi 1, 2, 3, 4, 5 , Shili Song 1, 2, 3, 4, 5 , Chunhui Xiao 1, 2, 3, 4, 5 , Jin Liang 1, 2, 3, 4, 5 , Bitao Dong 1, 2, 3, 4, 5 , Shujiang Ding 1, 2, 3, 4, 5
Affiliation  

For the first time, we design and synthesise a novel structure of hollow carbon nanosheets with MgAl-layered double hydroxide (MgAl-LDH) as the template and poly-dopamine (PDA) as the carbon source via a facile method. To reveal the significance of hollow carbon nanosheets, buffering large strains during the lithium de-intercalation cycle and prolonging the cycle life, SnO2@C nanocomposites as anode materials for lithium-ion batteries (LIBs) are prepared. As a result, the structure of hollow carbon nanosheets contributes to the improvement of the capacity and stability of the SnO2 anode material. The capacity of hollow SnO2@carbon nanosheets remains 693 mA h g−1 after 450 cycles with the current density of 0.5 A g−1 far better than that of pristine SnO2.

中文翻译:

N掺杂空心碳纳米片负载的SnO 2纳米粒子

首次,我们设计并合成中空碳纳米片与镁铝-层状双氢氧化物(镁铝-LDH)的新结构为模板和聚多巴胺(PDA)作为碳源通过的简便方法。为了揭示中空碳纳米片的重要性,在锂脱嵌循环过程中缓冲大应变并延长循环寿命,制备了SnO 2 @C纳米复合材料作为锂离子电池(LIB)的负极材料。结果,中空碳纳米片的结构有助于SnO 2负极材料的容量和稳定性的提高。中空SnO 2 @碳纳米片的容量仍为693 mA hg -1在450次循环后,电流密度为0.5 A g -1远优于原始的SnO 2
更新日期:2017-09-07
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