Design, Synthesis, and Reactivity of Multidentate Ligands with Rhenium(I) and Rhenium(V) Cores,European Journal of Inorganic Chemistry

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Design, Synthesis, and Reactivity of Multidentate Ligands with Rhenium(I) and Rhenium(V) Cores
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2017-09-07 11:02:08 , DOI: 10.1002/ejic.201700632
Jin-Hui Wang _{1,

2} , Romain Eychenne _{1,

2} , Mariusz Wolff ₃ , Sonia Mallet-Ladeira ₄ , Nicolas Lepareur ₅ , Eric Benoist _{1,

2}

Affiliation

The coordination behavior of three potentially N₃O-tetradentate ligands towards different rhenium cores (oxidation states +I and +V) are investigated. L₁H and L₂H lead to the formation of unexpected mononuclear tricarbonylrhenium(I) complexes of the general formula [(LH)Re(CO)₃Cl] (L = L₁ or L₂), whereas L₃H₃ gives the mononuclear complex [(L3)ReO] and its corresponding ^99mTc complex in good yield.

中文翻译：

dent（I）和hen（V）核的多齿配体的设计，合成和反应性

研究了三种潜在的N ₃ O-四齿配体对不同different核（氧化态+ I和+ V）的配位行为。L ₁ H和L ₂ H导致形成意想不到的通式[（LH）Re（CO）₃ Cl]的单核三羰基hen（I）配合物（L = L ₁或L ₂），而L ₃ H ₃给出单核络合物[（L3）ReO]及其相应的^99m Tc络合物收率良好。

更新日期：2017-09-07

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