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It's Getting Tight: Highly Substituted Intramolecularly P=OSn Coordinated Ferrocene Derivatives
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2017-09-07 11:00:36 , DOI: 10.1002/ejic.201700914 Bastian Nayyar 1 , Ramid Kapoor 1 , Michael Lutter 1 , Hazem Alnasr 1 , Klaus Jurkschat 1
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2017-09-07 11:00:36 , DOI: 10.1002/ejic.201700914 Bastian Nayyar 1 , Ramid Kapoor 1 , Michael Lutter 1 , Hazem Alnasr 1 , Klaus Jurkschat 1
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An elegant stepwise metalation of 1,2-bis(phosphonyl)ferrocene and subsequent reactions with organotin halides gave access to 1,2,3-tri- and 1,2,3,4-tetrasubstituted ferrocene derivatives. These show intramolecular P=O![[RIGHTWARDS ARROW]](http://onlinelibrarystatic.wiley.com/undisplayable_characters/002192.gif)
Sn interactions and serve as starting materials for further derivatizations giving, for example, organostannylium salts such as 11.
中文翻译：
越来越紧：分子内高度取代的P = OSn配位的二茂铁衍生物
对1,2-双（膦酰基）二茂铁进行精细的逐步金属化，然后与有机锡卤化物反应，可以得到1,2,3-三-和1,2,3,4-四取代的二茂铁衍生物。这些显示出分子内的P = OSn相互作用，并用作进一步衍生化的原料，例如提供有机锡盐，如11。
更新日期：2017-09-07
Sn interactions and serve as starting materials for further derivatizations giving, for example, organostannylium salts such as 11.
中文翻译：
越来越紧：分子内高度取代的P = OSn配位的二茂铁衍生物
对1,2-双（膦酰基）二茂铁进行精细的逐步金属化，然后与有机锡卤化物反应，可以得到1,2,3-三-和1,2,3,4-四取代的二茂铁衍生物。这些显示出分子内的P = O
Sn相互作用，并用作进一步衍生化的原料，例如提供有机锡盐，如11。
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