当前位置: X-MOL 学术Eur. J. Inorg. Chem. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
It's Getting Tight: Highly Substituted Intramolecularly P=OSn Coordinated Ferrocene Derivatives
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2017-09-07 11:00:36 , DOI: 10.1002/ejic.201700914
Bastian Nayyar 1 , Ramid Kapoor 1 , Michael Lutter 1 , Hazem Alnasr 1 , Klaus Jurkschat 1
Affiliation  

An elegant stepwise metalation of 1,2-bis(phosphonyl)ferrocene and subsequent reactions with organotin halides gave access to 1,2,3-tri- and 1,2,3,4-tetrasubstituted ferrocene derivatives. These show intramolecular P=O[RIGHTWARDS ARROW]Sn interactions and serve as starting materials for further derivatizations giving, for example, organostannylium salts such as 11.

中文翻译:

越来越紧:分子内高度取代的P = OSn配位的二茂铁衍生物

对1,2-双(膦酰基)二茂铁进行精细的逐步金属化,然后与有机锡卤化物反应,可以得到1,2,3-三-和1,2,3,4-四取代的二茂铁衍生物。这些显示出分子内的P = O [向右箭头]Sn相互作用,并用作进一步衍生化的原料,例如提供有机锡盐,如11
更新日期:2017-09-07
down
wechat
bug