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Thiophene-Extended Nickel Thiazoledithiolene: π-Extended Fused-Ring Metal Dithiolenes with Stabilized Frontier Orbitals
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2017-09-06 , DOI: 10.1002/ejic.201700702 Eric J. Uzelac 1 , Seth C. Rasmussen 1
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2017-09-06 , DOI: 10.1002/ejic.201700702 Eric J. Uzelac 1 , Seth C. Rasmussen 1
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The preparation of tetrabutylammonium bis[2-(2-thienyl)-4,5-thiazoledithiolato]nickelate(1–) is presented as the first example of a new family of π-extended fused-ring metal dithiolenes. The optical, electronic, and structural properties of this complex have been characterized by UV/Vis-NIR spectroscopy, cyclic voltammetry, and X-ray crystallography. Comparison of these properties to the analogous nickel thiophenedithiolene shows that incorporation of nitrogen into the fused ring stabilizes the frontier orbitals of the thiazole-based complex, while preserving the planar geometry, electronic delocalization, and low-energy NIR absorption of the previous thiophene-based species.
中文翻译：
Thiophene-Extended Nickel Thiazoledithiolene: π-Extended Fused-Ring-Ring Metal Dithiolenes with Stabilized Frontier Orbitals
四丁基铵双[2-(2-噻吩基)-4,5-噻唑二硫醇基]镍酸盐(1-)的制备是作为一个新的π-扩展稠环金属二硫烯家族的第一个例子。这种复合物的光学、电子和结构特性已通过 UV/Vis-NIR 光谱、循环伏安法和 X 射线晶体学表征。将这些特性与类似的噻吩二噻吩镍进行比较表明，将氮结合到稠环中可以稳定噻唑基复合物的前线轨道，同时保留先前基于噻吩的复合物的平面几何形状、电子离域和低能 NIR 吸收物种。
更新日期：2017-09-06
中文翻译：
Thiophene-Extended Nickel Thiazoledithiolene: π-Extended Fused-Ring-Ring Metal Dithiolenes with Stabilized Frontier Orbitals
四丁基铵双[2-(2-噻吩基)-4,5-噻唑二硫醇基]镍酸盐(1-)的制备是作为一个新的π-扩展稠环金属二硫烯家族的第一个例子。这种复合物的光学、电子和结构特性已通过 UV/Vis-NIR 光谱、循环伏安法和 X 射线晶体学表征。将这些特性与类似的噻吩二噻吩镍进行比较表明，将氮结合到稠环中可以稳定噻唑基复合物的前线轨道，同时保留先前基于噻吩的复合物的平面几何形状、电子离域和低能 NIR 吸收物种。
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