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Silver-catalyzed chemoselective annulation of propargyl amines with alkynes for access to pyridines and pyrroles
Tetrahedron ( IF 2.1 ) Pub Date : 2017-09-06 , DOI: 10.1016/j.tet.2017.09.002 Tauqir A. Nizami , Ruimao Hua
中文翻译:
炔烃与炔烃的银催化化学选择性环化反应,可得到吡啶和吡咯
更新日期:2017-09-06
Tetrahedron ( IF 2.1 ) Pub Date : 2017-09-06 , DOI: 10.1016/j.tet.2017.09.002 Tauqir A. Nizami , Ruimao Hua
The annulation of propargyl amines with electron-deficient alkynes in the presence of silver salts affording pyridines and pyrroles has been developed. The chemoselective [4+2] or [3+2] annulation approach to pyridines or pyrroles depends on the structures of propargyl amines and the different reaction conditions.
中文翻译:
炔烃与炔烃的银催化化学选择性环化反应,可得到吡啶和吡咯
已经开发了在存在吡啶和吡咯的银盐存在下,炔丙基胺与缺电子炔烃的环化反应。吡啶或吡咯的化学选择性[4 + 2]或[3 + 2]环化方法取决于炔丙基胺的结构和不同的反应条件。