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Enhancement of the dielectric permittivity and magnetic properties of Dy substituted strontium titanate ceramics
Journal of the European Ceramic Society ( IF 5.7 ) Pub Date : 2017-09-06 , DOI: 10.1016/j.jeurceramsoc.2017.09.007
Alexander Tkach , João S. Amaral , Sebastian Zlotnik , Vítor S. Amaral , Paula M. Vilarinho

Structural, dielectric and magnetic properties of dense Dy-substituted strontium titanate ceramics are investigated. In the Sr1-1.5xDyxTiO3 system, incorporation of Dy onto the Sr site is confirmed by a linear decrease of the lattice parameter up to x = 0.05. Dielectric spectroscopy analysis of Sr1-1.5xDyxTiO3 ceramics reveals four relaxations. Two relaxations observed below 55 K are attributed to dipoles formed by off-centre displacement of Dy3+ ions on the Sr sites. Other two dielectric relaxations found at higher temperatures are attributed to the oxygen vacancy related mechanisms. As result, very high dielectric permittivity of ∼33500 at 28 K and of ∼9600 around room temperature at moderate dissipation factor of ∼0.02 are obtained for Sr0.985Dy0.01TiO3 ceramics, making it a promising material for capacitor electronic applications. Paramagnetic behaviour observed for Sr1-1.5xDyxTiO3 as well as for Sr1-xDy2xTi1-xO3 ceramics indicates impossibility to induce a magnetic order and hence magnetoelectric coupling in strontium titanate by Dy substitution.



中文翻译:

Dy取代钛酸锶锶陶瓷的介电常数和磁性能的提高

研究了致密的Dy-取代钛酸锶锶陶瓷的结构,介电和磁性能。在Sr 1-1.5 x Dy x TiO 3系统中,通过将晶格参数线性降低至x  = 0.05 ,可以确定将Dy掺入Sr位点。Sr 1-1.5 x Dy x TiO 3陶瓷的介电谱分析显示出四张弛豫。在55 K以下观察到的两个弛豫归因于Dy 3+的偏心位移形成的偶极子离子在Sr位点上。在较高温度下发现的其他两种介电弛豫归因于与氧空位有关的机理。结果,对于Sr 0.985 Dy 0.01 TiO 3陶瓷,获得了很高的介电常数,在28 K时约为33500,在室温下约为9600,在中等损耗因子约为0.02的情况下,使其成为电容器电子应用的有前途的材料。观察到Sr 1-1.5 x Dy x TiO 3以及Sr 1- x Dy 2 x Ti 1- x O 3的顺磁行为 陶瓷表明不可能通过Dy取代在钛酸锶中诱导磁序,从而磁电耦合。

更新日期:2017-09-06
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