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Morphology controllable time-dependent CoS nanoparticle thin films as efficient counter electrode for quantum dot-sensitized solar cells
Chemical Physics Letters ( IF 2.8 ) Pub Date : 2017-09-06 , DOI: 10.1016/j.cplett.2017.09.001
Araveeti Eswar Reddy , S. Srinivasa Rao , Chandu V.V.M. Gopi , Tarugu Anitha , Chebrolu Venkata Thulasi-Varma , Dinah Punnoose , Hee-Je Kim

Cobalt sulfide (CoS) agglomerated nanoparticle thin films obtained by a facile chemical bath method at different deposition times. The CoS counter electrode (CE) deposited at 3 h deposition time (CC-3h) based quantum dot sensitized solar cells (QDSSCs) achieves higher power conversion efficiency (η) of 3.67% than those of CC-2h (1.83%), CC-4h (2.52%), and Pt (1.48%) CEs, under one sun illumination (100 mW cm-2, AM 1.5 G). The electrochemical analysis revealed that CC-3h CE shows a smaller charge transfer resistance (9.22 Ω) at the CE/electrolyte interface than the CC-2h (23.34 Ω), CC-4h (19.73 Ω) and Pt (139.92 Ω) CEs, respectively.

中文翻译:

形态学可控的时间依赖性CoS纳米薄膜作为量子点敏化太阳能电池的有效对电极

通过简便的化学浴法在不同的沉积时间下获得的硫化钴(CoS)团聚纳米颗粒薄膜。基于3小时沉积时间(CC-3h)的量子点敏化太阳能电池(QDSSCs)沉积的CoS对电极(CE)实现的能量转换效率(η)比CC-2h(1.83%),CC更高在1个日光照射下(100 mW cm -2,AM 1.5 G)-4h(2.52%)和Pt(1.48%)CEs 。电化学分析表明,CC-3h CE在CE /电解质界面处显示出比CC-2h(23.34Ω),CC-4h(19.73Ω)和Pt(139.92Ω)CE小的电荷转移电阻(9.22Ω),分别。
更新日期:2017-09-07
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