Indole–Indole Ullmann Cross-Coupling for CAr–N Bond Formation: Total Synthesis of (–)-Aspergilazine A,European Journal of Organic Chemistry

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Indole–Indole Ullmann Cross-Coupling for CAr–N Bond Formation: Total Synthesis of (–)-Aspergilazine A
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2017-09-06 02:35:46 , DOI: 10.1002/ejoc.201700842
Iago Alonso ₁ , Rosana Alvarez ₁ , Ángel R. de Lera ₁

Affiliation

A new synthetic approach to the heterodimeric bis-Trp/Pro-diketopiperazine alkaloid (–)-aspergilazine A is developed. The method is based on the previously optimized Cu^I-catalyzed C_Ar–N Ullmann coupling of indole units.

中文翻译：

CAr–N键形成的吲哚-吲哚乌尔曼交叉偶联：（-）-曲霉嗪A的全合成

开发了一种新的合成方法，用于异二聚体bis-Trp / Pro-diketopiperazine生物碱（-）-aspergilazineA。该方法基于先前优化的Cu ^I催化的吲哚单元的C _Ar -N Ullmann偶联。

更新日期：2017-09-06

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