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Protonation of Coordinated Dinitrogen Using Protons Generated from Molecular HydrogenProtonation of Coordinated Dinitrogen Using Protons Generated from Molecular Hydrogen
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2017-09-06 09:43:04 , DOI: 10.1002/ejic.201700784
Masilamani Tamizmani 1 , Chinnappan Sivasankar 1
Affiliation  

The coordinated dinitrogen in the W(P–P) complex can be protonated using protons from H2, split into protons and hydrides using the frustrated Lewis pair concept, under normal experimental conditions (room temp., 1 atm). The reaction progress of the N2 protonation was monitored by spectroscopic and analytical techniques.

中文翻译:

用分子氢产生的质子使配位二氮质子化用分子氢产生的质子使配位二氮质子化

在正常实验条件(室温,1个大气压)下,可以使用来自H 2的质子将W(P-P)络合物中的配位二氮质子化,并使用沮丧的Lewis对概念将其分解为质子和氢化物。通过光谱和分析技术监测N 2质子化的反应进程。
更新日期:2017-09-06
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