Metal–Organic Frameworks as Supramolecular Templates for Directing Aromatic Packing Motifs,Crystal Growth & Design

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Metal–Organic Frameworks as Supramolecular Templates for Directing Aromatic Packing Motifs
Crystal Growth & Design ( IF 3.2 ) Pub Date : 2017-09-05 00:00:00 , DOI: 10.1021/acs.cgd.7b00954
Liubov M. Lifshits ₁ , Matthias Zeller ₂ , Charles F. Campana ₃ , Jeremy K. Klosterman ₁

Affiliation

Modular methods to direct the molecular packing of aromatic organic chromophores are essential for understanding the subtle principles needed to predict intermolecular interactions and design uniform, efficient organic optoelectronic devices. Here we demonstrate that layered two-dimensional metal–organic frameworks, based on the copper paddlewheel and 5-aryl isophthalate ligands, can alter the interstitial packing of the aryl groups and template new packing motifs for the small acenes.

中文翻译：

金属有机框架作为指导芳香包装图案的超分子模板

指导芳香族有机发色团分子堆积的模块化方法对于理解预测分子间相互作用和设计均匀，有效的有机光电器件所需的微妙原理至关重要。在这里，我们证明了基于铜桨轮和间苯二甲酸5-芳基酯配体的二维二维金属有机骨架可以改变芳基的填隙堆积，并为小丁烷设计新的堆积图案。

更新日期：2017-09-06

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