Transition Metal Complexes of a Monocarba-closo-dodecaborate Ligand via B–H Activation,European Journal of Inorganic Chemistry

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Transition Metal Complexes of a Monocarba-closo-dodecaborate Ligand via B–H Activation
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2017-09-05 01:10:47 , DOI: 10.1002/ejic.201700677
Yunjun Shen ₁ , Jiyong Liu ₁ , Tosaporn Sattasatchuchana ₂ , Kim K. Baldridge ₂ , Simon Duttwyler ₁

Affiliation

Rhodium and palladium complexes of the monocarba-closo-dodecaborate cluster are reported. These products were formed by amide-group-assisted B–H activation and feature direct B2–[TM] bonds. Full characterization by spectroscopic methods and X-ray crystallography, as well as calculations, were performed.

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