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Characterization of nickel manganite NTC thermistor films prepared by aerosol deposition at room temperature
Journal of the European Ceramic Society ( IF 5.8 ) Pub Date : 2017-09-05 , DOI: 10.1016/j.jeurceramsoc.2017.09.005
Michaela Schubert , Christian Münch , Sophie Schuurman , Véronique Poulain , Jaroslaw Kita , Ralf Moos

NiMn2O4+δ thermistor thick films have been successfully deposited by the so-called Aerosol Deposition Method (ADM) at room temperature on alumina substrates, Si-wafers, as well as on special planar four-wire interdigital electrode structures for high-precision electrical characterization. The NTCR films are homogeneous, completely dense and scratch resistant. Both as-deposited and tempered, the NTCR films exhibit a cubic spinel structure. Between 25 °C and 90 °C, the NTCR film resistance behaves as it is typical for variable range hopping (VRH) with parabolic density of states. As a result of moderate film tempering, the thermistor constant B and the specific resistance at 25 °C (ρ25) decrease from 4250 K to 4020 K and 65 Ω·m to 40 Ω·m respectively, and are close to bulk values. In combination with the excellent reproducibility of the ρ25 and B values, AD processing of films appears to be a promising alternative for classical ceramic bulk processes.



中文翻译:

室温下气溶胶沉积法制备的锰锰NTC热敏电阻镍膜的表征

NiMn 2 O 4 +δ热敏电阻厚膜已通过所谓的气溶胶沉积法(ADM)在室温下成功地沉积在氧化铝基板,硅晶片以及特殊的平面四线叉指式电极结构上,以实现高电阻率。精密的电气特性。NTCR薄膜均匀,完全致密且耐刮擦。无论是沉积的还是回火的,NTCR膜均显示立方尖晶石结构。在25°C至90°C之间,NTCR膜电阻的行为与具有抛物线状态密度的可变范围跳变(VRH)的典型情况相同。为中等薄膜回火,热敏电阻常数的结果并在25℃下的电阻率(ρ 25)分别从4250 K减小到4020 K,从65Ω·m减小到40Ω·m,并且接近体积值。与所述的优异的再现性组合ρ 25值,薄膜的AD处理似乎是经典的陶瓷本体方法有希望的替代物。

更新日期:2017-09-05
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