An efficient one-pot cascade methodology for the synthesis of (ethoxycarbonyl)difluoromethyl thioethers is described. Benzyl, allyl, alkyl halides or diazonium salts as the starting materials together with thiocyanate sodium and TMS-CF₂CO₂Et in the presence of CsF or NaOAc afford a variety of the fluoroalkylthiolated products in moderate to good yields.

中文翻译：

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由硫氰酸钠和2-（三甲基甲硅烷基）-2,2-二氟乙酸乙酯（TMS-CF ₂ CO ₂ Et）一锅合成（乙氧基羰基）二氟甲基硫醚

描述了一种用于合成（乙氧基羰基）二氟甲基硫醚的有效的一锅级联方法。在CsF或NaOAc的存在下，以苄基，烯丙基，烷基卤化物或重氮盐为起始原料，与硫氰酸钠和TMS-CF ₂ CO ₂ Et一起，以中等至良好的收率提供了多种氟代烷基硫代产物。