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Assorted Interactions of Amino Acids Prevailing in Aqueous Vitamin C Solutions Probed by Physicochemical and Ab-Initio Contrivances
Chemical Physics Letters ( IF 2.8 ) Pub Date : 2017-09-02 , DOI: 10.1016/j.cplett.2017.08.054
Koyeli Das , Milan Chandra Roy , Biplab Rajbanshi , Mahendra Nath Roy

Qualitative and quantitative analysis of molecular interaction prevailing in Tyrosine and Tryptophan in aqueous solution of Vitamin C have been probed by thermophysical properties. The apparent molar volume (ϕV), viscosity B-coefficient, molal refraction (RM) of tyrosine and tryptophan have been studied in aqueous vitamin C solutions at diverse temperatures via Masson equation which deduced solute-solvent and solute-solute interactions, respectively. Spectroscopic study along with physicochemical and computational techniques provides lots of interesting and highly significant insights of the model biological systems. The overall results established strong solute-solvent interactions between studied amino acids and vitamin C mixture in the ternary solutions.

中文翻译:

物理化学和从头算起的探针探测到的维生素C水溶液中氨基酸的各种相互作用

通过热物理性质对定性和定量分析维生素C水溶液中酪氨酸和色氨酸中普遍存在的分子相互作用进行了研究。表观摩尔体积(ϕ V),通过Masson方程研究了维生素C水溶液在不同温度下酪氨酸和色氨酸的粘度B系数,摩尔折射(R M),分别推导了溶质-溶剂和溶质-溶质的相互作用。光谱研究以及物理化学和计算技术为模型生物系统提供了许多有趣且高度重要的见解。总体结果建立了三元溶液中所研究的氨基酸与维生素C混合物之间强大的溶质-溶剂相互作用。
更新日期:2017-09-04
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