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Plasma assisted nitrogen oxide production from air: Using pulsed powered gliding arc reactor for a containerized plant
AIChE Journal ( IF 3.5 ) Pub Date : 2017-08-31 14:16:58 , DOI: 10.1002/aic.15922
Bhaskar S. Patil 1 , F. J. J. Peeters 2 , Gerard J. van Rooij 2 , J. A. Medrano 3 , Fausto Gallucci 3 , J. Lang 4 , Qi Wang 1 , Volker Hessel 1
Affiliation  

The production of NOx from air and air + O2 is investigated in a pulsed powered milli-scale gliding arc (GA) reactor, aiming at a containerized process for fertilizer production. Influence of feed mixture, flow rate, temperature, and Ar and O2 content are investigated at varying specific energy input. The findings are correlated with high-speed imaging of the GA dynamics. An O2 content of 40–48% was optimum, with an enhancement of 11% in NOx production. Addition of Ar and preheating of the feed resulted in lower NOx production. Lower flow rates produced higher NOx concentrations due to longer residence time in the GA. The volume covered by GA depends strongly on the gas flow rate, emphasizing that the gas flow rate has a major impact on the GA dynamics and the reaction kinetics. For 0.5 L/min, 1.4 vol % of NOx concentration was realized, which is promising for a containerized process plant to produce fertilizer in remote locations. © 2017 American Institute of Chemical Engineers AIChE J, 2017

中文翻译:

从空气中产生等离子体辅助的一氧化氮:使用脉冲动力滑弧反应器处理集装箱式工厂

NO的产生X从空气和空气+ O 2以脉冲供电毫规模滑动弧(GA)的反应器进行了研究,目的在于对化肥生产一个集装箱处理。研究了在不同比能输入下进料混合物,流速,温度以及Ar和O 2含量的影响。这些发现与遗传算法动力学的高速成像相关。的O 2的40-48%的含量为最佳,11%在NO增强X生产。氩的加法和进料的预热导致较低的NO X的产生。较低的流速产生更高的NO X由于在GA中的停留时间较长,所以浓度较高。GA覆盖的体积在很大程度上取决于气体流速,强调气体流速对GA动力学和反应动力学具有重大影响。为0.5升/分钟,NO 1.4%(体积)X浓度实现,这是有前途的一个集装箱处理厂以生产肥料在远程位置。©2017美国化学工程师学会AIChE J,2017
更新日期:2017-09-04
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