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Cu/Cu2O nanoparticle interface: Rational designing of a heterogeneous catalyst system for selective hydroamination
Molecular Catalysis ( IF 3.9 ) Pub Date : 2017-08-16 , DOI: 10.1016/j.mcat.2017.05.028
Manideepa Sengupta , Subhasis Das , Ankur Bordoloi

One pot highly uniform Cu(0)-Cu(I) oxide nanoparticles (5–10 nm) have been synthesized on nitrogen rich mesoporous carbon nanospheres (Cu-NCN) and efficiently utilized as a heterogeneous catalyst towards hydroamination of aromatic terminal alkynes with aniline derivatives. The catalyst bed provides Cu2O nanoparticles stabilized by nitrogen functionalities in the carbon nanospheres, which triggers the catalytic system with significantly large Turn over number (TON) and >99% selectivity towards Markovnikov addition product. The structure and morphology of the copper nanoparticles engraved carbon spheres have been studied by performing nitrogen physisorption studies (BET), X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) characterization techniques.



中文翻译:

Cu / Cu 2 O纳米粒子界面:用于选择性加氢胺化的非均相催化剂体系的合理设计

一锅高度均匀的Cu(0)-Cu(I)氧化物纳米颗粒(5-10 nm)已在富氮介孔碳纳米球(Cu-NCN)上合成,并有效地用作异质催化剂,用于苯胺芳族末端炔烃的加氢胺化衍生品。催化剂床提供Cu 2碳纳米球中的氮官能团稳定了O纳米颗粒,从而触发了催化系统,该系统具有显着大的转换数(TON)和对Markovnikov加成产物具有> 99%的选择性。通过进行氮物理吸附研究(BET),X射线衍射(XRD),扫描电子显微镜(SEM),透射电子显微镜(TEM),X射线光电子能谱研究了刻有铜纳米颗粒的碳球的结构和形态(XPS)表征技术。

更新日期:2017-08-16
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