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Noble metal modified TiO2: selective photoreduction of CO2 to hydrocarbons
Molecular Catalysis ( IF 3.9 ) Pub Date : 2017-07-15 , DOI: 10.1016/j.mcat.2017.06.031
Nikita Singhal , Umesh Kumar

CO2 photoreduction is an indispensable tool to generate carbon containing fuel. A series of noble metal modified TiO2 were prepared using photodeposition method, and their photocatalytic activities were evaluated towards photocatalytic reduction of CO2 under gas phase conditions using water vapor as electron donor and UV-A light as energy source. TiO2 solely produce CO. The addition of noble metals to TiO2 via photodeposition method significantly increased the photocatalytic reduction of CO2 with change in product selectivity towards methane under identical conditions. Further combinations of two different noble metals were simultaneously deposited to develop bimetal/TiO2. The bimetal/TiO2 further enhances the methane yield with considerable amount of ethane. Ag1%Pd1%/TiO2 has been proven as best catalyst among all catalyst and yields maximum methane.



中文翻译:

贵金属改性的TiO 2:CO 2选择性光还原为烃

CO 2光还原是产生含碳燃料的必不可少的工具。采用光沉积法制备了一系列贵金属改性的TiO 2,并以水蒸气为电子给体,以UV-A光为能源,评价了它们在气相条件下对CO 2光催化还原的光催化活性。TiO 2仅产生CO。在相同条件下,通过光沉积法向TiO 2中添加贵金属会显着提高CO 2的光催化还原度,同时改变产品对甲烷的选择性。同时沉积两种不同贵金属的进一步组合以形成双金属/ TiO2。双金属/ TiO 2与大量的乙烷一起进一步提高了甲烷的产率。已证明Ag 1% Pd 1% / TiO 2是所有催化剂中最好的催化剂,并产生最大的甲烷。

更新日期:2017-07-15
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