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Performance and stability in H2S of SrFe0.75Mo0.25O3-δ as electrode in proton ceramic fuel cells
Journal of the European Ceramic Society ( IF 5.7 ) Pub Date : 2017-08-26 , DOI: 10.1016/j.jeurceramsoc.2017.08.020
S. Wachowski , Z. Li , J.M. Polfus , T. Norby

The H2S-tolerance of SrFe0.75Mo0.25O3-δ (SFM) electrodes has been investigated in symmetric proton ceramic fuel cells (PCFC) with BaZr0.8Ce0.1Y0.1O3-δ (BZCY81) electrolyte. The ionic conductivity of the electrolyte under wet reducing conditions was found to be insignificantly affected in the presence of up to 5000 ppm H2S. The fuel cell exhibited an OCV of about 0.9 V at 700 °C, which dropped to about 0.6 V and 0.4 V upon exposure to 500 and 5000 ppm H2S, respectively, on the fuel side. Post characterization of the fuel cell revealed significant degradation of the anode in terms of microstructure and chemical composition due to formation of sulfides such as SrS, MoS2 and Fe3S4. Nevertheless, the fuel cell was still functional due to the sufficient electronic conductivity of some of these sulfides.



中文翻译:

SrFe 0.75 Mo 0.25 O3 在质子陶瓷燃料电池中作为电极在H 2 S中的性能和稳定性

在具有BaZr 0.8 Ce 0.1 Y 0.1 O3 (BZCY81)电解质的对称质子陶瓷燃料电池(PCFC)中,已经研究了SrFe 0.75 Mo 0.25 O3 (SFM)电极的H 2 S耐受性。发现在存在高达5000 ppm H 2 S的情况下,在湿还原条件下电解质的离子电导率几乎没有受到影响。燃料电池在700°C时的OCV约为0.9 V,降至约0.6 V时,OCV降低。暴露于500和5000 ppm H 2时为0.4 VS分别在燃料侧。燃料电池的后期表征显示,由于硫化物(如SrS,MoS 2和Fe 3 S 4)的形成,阳极在微观结构和化学组成方面均显着降低。尽管如此,由于其中一些硫化物具有足够的电子传导性,燃料电池仍能正常工作。

更新日期:2017-08-26
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