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Highly Active Manganese-Mediated Acylation of Alcohols with Acid Chlorides or Anhydrides
Synlett ( IF 2 ) Pub Date : 2017-08-24 , DOI: 10.1055/s-0036-1590973
Seung-Hoi Kim , Seong-Ryu Joo , Young-Jin Youn , Young-Ran Hwang

To explore further the practical uses of highly active manganese (Mn*), a variety of alcohols were treated with Mn*, and the resulting complexes were coupled with acid chlorides and/or acetic anhydride in the absence of any extra catalyst. The subsequent reactions took place smoothly under mild conditions, providing the corresponding O-acylation products in good to excellent isolated yields.

中文翻译:

醇与酰氯或酸酐的高活性锰介导酰化

为了进一步探索高活性锰 (Mn*) 的实际用途,用 Mn* 处理各种醇,在没有任何额外催化剂的情况下,将所得配合物与酰氯和/或乙酸酐偶联。随后的反应在温和的条件下顺利进行,提供了相应的 O-酰化产物,分离产率良好至极好。
更新日期:2017-08-24
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