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Organometallic mechanisms: Measuring up with the early metals
Nature Chemistry ( IF 19.2 ) Pub Date : 2017-08-24 , DOI: 10.1038/nchem.2851 Ian A. Tonks
Nature Chemistry ( IF 19.2 ) Pub Date : 2017-08-24 , DOI: 10.1038/nchem.2851 Ian A. Tonks
Organometallic mechanisms: Measuring up with the early metals
中文翻译:
有机金属机制:掌握早期金属
有机金属机制:掌握早期金属
更新日期:2017-09-07
Nature Chemistry, Published online: 24 August 2017; doi:10.1038/nchem.2851
Mathematically modelling metal–ligand bonding in late transition-metal complexes has been an important tool in catalyst development — although lacking for early transition metals such as Cr and Ti. Now, a simple method for measuring ligand donor properties promises to elevate high-valent early transition metal catalysis to the same level.
中文翻译:
有机金属机制:掌握早期金属
有机金属机制:掌握早期金属
《自然化学》,在线发布:2017年8月24日; doi:10.1038 / nchem.2851
在后期过渡金属络合物中对金属-配体键进行数学建模一直是催化剂开发的重要工具,尽管早期过渡金属(例如Cr和Ti)缺乏这种方法。现在,一种用于测量配体供体性质的简单方法有望将高价早期过渡金属催化作用提高到相同水平。