Abstract

In recent years, the C–H bond activation field has known very fast expansion offering valuable synthetic tools. Consequently, the quest for new approaches to afford atom- and step-economical processes has driven the scientific community to imagine original strategies. In this context, the direct functionalization of substrates by a transition-metal-catalyzed C–H bond activation using a transient directing group has emerged as a promising approach. This short review focuses on the major progress made in this field to provide to the reader an overview of the recent advances.

1 Introduction

2 From a Historical Point of View

3 Functionalization of Carbonyl Derivatives

4 Functionalization of Amines Derivatives

5 Summary and Outlook

In recent years, the C–H bond activation field has known very fast expansion offering valuable synthetic tools. Consequently, the quest for new approaches to afford atom- and step-economical processes has driven the scientific community to imagine original strategies. In this context, the direct functionalization of substrates by a transition-metal-catalyzed C–H bond activation using a transient directing group has emerged as a promising approach. This short review focuses on the major progress made in this field to provide to the reader an overview of the recent advances.

1 Introduction

2 From a Historical Point of View

3 Functionalization of Carbonyl Derivatives

4 Functionalization of Amines Derivatives

5 Summary and Outlook

中文翻译：

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瞬态指导群策略：过渡金属催化的CH键功能化的新趋势

摘要

近年来，C–H键激活领域迅速发展，提供了有价值的合成工具。因此，寻求新的方法来提供原子经济和逐步经济的过程已促使科学界想象出原始的策略。在这种情况下，通过过渡金属催化的C–H键活化（使用瞬态导向基团）对底物进行直接功能化已成为一种有前途的方法。这篇简短的评论重点介绍了该领域的主要进展，以向读者提供最新进展的概述。

1引言

2从历史的角度看

3羰基衍生物的官能化

4胺衍生物的功能化

5总结与展望

近年来，C–H键激活领域迅速发展，提供了有价值的合成工具。因此，寻求新的方法来提供原子经济和逐步经济的过程已促使科学界想象出原始的策略。在这种情况下，通过过渡金属催化的C–H键活化（使用瞬态导向基团）对底物进行直接功能化已成为一种有前途的方法。这篇简短的评论重点介绍了该领域的主要进展，以向读者提供最新进展的概述。

1引言

2从历史的角度看

3羰基衍生物的官能化

4胺衍生物的功能化

5总结与展望