Isotope Studies in Oxidation of Propane over Vanadium Oxide,ChemCatChem

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Isotope Studies in Oxidation of Propane over Vanadium Oxide
ChemCatChem ( IF 3.8 ) Pub Date : 2017-08-23 05:15:38 , DOI: 10.1002/cctc.201700847
Pierre Kube ₁ , Benjamin Frank _{1,

2} , Robert Schlögl ₁ , Annette Trunschke ₁

Affiliation

Roadmap to value or waste: The reaction network of propane oxidation over vanadium oxide catalysts was analyzed by using temperature-programmed reactions and experiments with D- and ¹³C-labeled propane molecules. Propylene formation and oxidation of acrolein strongly depend on the nature of the catalyst. Surface density of vanadyl groups and nature of electrophilic oxygen species are relevant with regard to selectivity.

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