Ir(III)-Catalyzed site-selective amidation of azoxybenzenes and late-stage transformation,Organic Chemistry Frontiers

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Ir(III)-Catalyzed site-selective amidation of azoxybenzenes and late-stage transformation
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2017-08-11 00:00:00 , DOI: 10.1039/c7qo00542c
Wenge Zhang _{1,

2,

3,

4} , Hong Deng _{1,

2,

3,

4} , Hongji Li _{1,

2,

3,

4}

Affiliation

An efficient ortho C–H amidation of azoxybenzenes with 1,4,2-dioxazol-5-ones under Ir(III)-catalysis has been developed. This simple amidation reaction provides a new protocol for the diversification of azoxybenzenes, and affords the aminated products in moderate to good yields. Meanwhile, an investigation of the late-stage transformation of products is also presented in this text.

中文翻译：

Ir（III）催化的乙氧基苯的位点选择性酰胺化和后期转化

一种有效的邻位C-H azoxybenzenes与-1,4,2-二恶唑-5-酮下的Ir（酰胺化III）-catalysis已经研制成功。这种简单的酰胺化反应为多样化的乙氧基苯提供了新的方案，并以中等至良好的收率提供了胺化产物。同时，本文还对产品的后期转型进行了研究。

更新日期：2017-08-23

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