Identifying a cobalt catalyst for highly selective hydrosilylation of allenes,Organic Chemistry Frontiers

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Identifying a cobalt catalyst for highly selective hydrosilylation of allenes
Organic Chemistry Frontiers ( IF 5.4 ) Pub Date : 2017-07-18 00:00:00 , DOI: 10.1039/c7qo00497d
Zheng Yang _{1,

2,

3,

4,

5} , Dongjie Peng _{1,

2,

3,

4,

5} , Xiaoyong Du _{1,

2,

3,

4,

5} , Zheng Huang _{1,

2,

3,

4,

5} , Shengming Ma _{1,

2,

3,

4,

5}

Affiliation

An efficient method of cobalt-catalyzed allene-hydrosilylation is developed. The reaction enjoys an excellent regio- and stereoselectivity and a broad scope affording Z-allylic silanes. Many synthetically useful functional groups can be tolerated. A Co(I)-species involved mechanism is proposed.

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